Can I "train" my scalp to become less oily by washing less often?
No. Sebaceous glands produce sebum under hormonal and thermal control; they do not have a thermostat that shuts off when oil sits on your roots. While avoiding overly harsh cleansers prevents barrier irritation, stretching washes for a week when you have a naturally oily scalp simply leaves oxidized lipids on the skin, inviting itchiness.